Jian Liu

Associate Professor (Tenure)

Mechanical

Other Titles: Principal's Research Chair in Energy Storage Technologies
Office: EME3223
Phone: 250.807.8708
Email: jliu13@mail.ubc.ca

Research Summary

Advanced nanofabrication; Nanomaterials and nanotechnology; Energy storage systems; Next-generation batteries

Courses & Teaching

Material Science for Engineers - APSC 259; Mechanics of Materials I - APSC 260

Biography

Jian Liu completed a B.Eng. degree in Metallic Materials Engineering at Sichuan University in 2006, an M.Eng. in Materials Science and Engineering at University of Science and Technology Beijing in 2009, and a Ph.D. in Materials Science at the University of Western Ontario in 2013 with Prof. Xueliang (Andy) Sun. Prior to joining UBC in Jan 2017, he was a postdoctoral fellow in Energy and Environment Directorate at Pacific Northwest National Laboratory (PNNL, 2015-2016), and Advanced Light Source at Lawrence Berkeley National Laboratory (2014-2015). Dr. Liu is the recipient of the prestigious NSERC Postdoctoral Fellowship Award (2014-2016), a PNNL Alternated-Sponsored Fellowship (2015-2016), the Mitacs Elevate Postdoctoral Fellowship Award (2013-2014), and the Chinese Government Award for Outstanding Self-Financed Students Abroad (2013).

Websites

Advanced Materials for Energy Storage Lab

Degrees

2009-2013, Ph.D., University of Western Ontario
2006-2009, M. Eng., University of Science and Technology Beijing
2002-2006, B. Eng., Sichuan University

Research Interests & Projects

1. Atomic/Molecular Layer Deposition (ALD/MLD)
This research theme emphasizes on the surface chemistry and process development for inorganic, organic, and hybrid inorganic/organic thin films and particles by using advanced atomic layer deposition (ALD) and molecular layer deposition (MLD), and on the exploration of these functional nanomaterials in various emerging fields, such as energy storage and conversion (batteries, fuel cells, solar cells), gas sensors, optical etc.  ALD and MLD are very powerful techniques for controlling materials deposition with subatomic precision. During an ALD or MLD process, gas-phase precursors are sequentially exposed to the substrate, and surface reactions occurring at the substrates are self-limiting and saturated. This reaction mechanism renders ALD or MLD deposited thin films several advantages, such as precisely controlled thickness, excellent uniformity and conformity, and tunable composition, which hold great promises for many unexplored applications.

Figure 1. Illustration of (a) ALD for inorganic films and (b) MLD for hybrid inorganic-organic films.

2. Surface/Interface in Energy Systems
This research theme focuses on the control and modification of surface and interface at nanoscale in energy storage and conversion systems, and on the fundamental understanding of interfacial properties and phenomena using advanced in-situ and ex-situ characterization techniques, including synchrotron radiation, XRD, HRTEM. For example, Li-ion batteries are the dominant energy storage technology that power today’s electric vehicles. One common problem in Li-ion batteries is unfavorable side reactions at the electrode/electrolyte interface, which results in rapid performance degradation in Li-ion batteries and hinder their future applications for transportation. This research is to use nanoscale surface coatings on electrode materials in order to prevent these side reactions between electrode and electrolyte, thereby improving the overall performance of Li-ion batteries, especially at extreme working conditions such as high temperatures.

Figure 2. Ideal surface coating layer at electrode-electrolyte interfaces in Li-ion batteries.

3. Electrode and Electrolyte Materials for Beyond Li-ion Batteries
This research theme focuses on the discovery, synthesis,  characterization, and applications of new electrode and solid-state electrolyte materials in beyond Li-ion batteries, such as Li-S, Na-ion batteries, as promising alternatives to present Li-ion chemistry for electric vehicles.

• Na-ion batteries

The growing global market for Li-ion batteries has raised concerns about the feasibility of lithium, due to its low abundance in the Earth’s crust (0.006 wt%). The increasing demand for lithium-containing electrode materials will drive up the price of lithium precursors (such as Li2CO3), ultimately making lithium-ion technology expensive. In this regard, Na-ion batteries are promising cheaper alternative, because of the high abundance of sodium (2.4wt% on Earth), the wide availability and low cost of sodium precursors. However, the relatively large ionic radius of the Na ion (1.06Å vs. 0.76Å of Li ion) could cause larger structural distortions and higher diffusion barriers in the host materials during charge/discharge cycling. The theme of this research is this problem could be addressed by preparing nanosize electrode materials and reducing the diffusion length of Na ions.Figure 3. (left) sodium titanate anode for Na-ion batteries; (center) In-situ high-temperature XRD showing the phase evolution from TiO2 to Na0.23TiO2; (right) Synchradiation radiation mapping indicating phase distribution and boundary between TiO2 to Na0.23TiO2.

3D Microbatteries

Three-dimensional (3D) all-solid-state microbatteries have been seen as promising on-board energy storage systems for microelectronics, wearable and flexible devices, and medical implants, due to their high energy and power densities. However, fabrication of 3D microbatteries has been shown to be extremely challenging for conventional deposition techniques. In this context, ALD is being considered as the most promising technique for 3D microbatteries due to its exclusive advantages of depositing pinhole-free and uniform battery material thin films onto 3D substrates. This research theme is to apply the powerful ALD technique to develop key component materials, such as electrode and solid-state electrolytes, and eventually fabricate real 3D all-solid-state microbatteries.

Figure 4. Hierarchical CNTs@FePO₄ Architecture as a 3D Electrode for Lithium-Ion and Sodium-Ion Batteries

Selected Publications & Presentations

Full publication list (Google Scholar; Citation: 2268; H-index: 25)

2018

60. J. Liu, D. Lv, J. Zheng, P. Yan, B. Wang, X. Sun, Y. Shao, C. Wang, J.-G. Zhang, and J. Liu, “Minimizing polysulfide shuttle effect in lithium-ion sulfur batteries by anode surface passivation”, 2018, ACS Appl. Mater. Interfaces, revised.

59. Y. Liu, J. Liu, J. Wang, M. Banis, B. Xiao, A. Lushington, W. Xiao, R. Li, T-K Sham, G. Liang, X. Sun, “Evidence of size-dependent conductive phase on lithium iron phosphate during carbon coating”, Nat. Commun. 2018, 9, 929.

58. J. Liu, H. Zhu, and M. Shiraz,  “Towards 3D Solid-State Batteries via Atomic Layer Deposition Approach”, 2018, Front. Energy Res. doi: 10.3389/fenrg.2018.00010

2017

57. B. Xiao, B. Wang, J. Liu, K. Kaliyappan, Q. Sun, Y. Liu, G. Dadheech, M.P. Balogh, L. Yang, TK Sham, R. Li, M. Cai, X. Sun, “Highly stable Li_1.2Mn_0.54Co_0.13Ni_0.13O₂ enabled by novel atomic layer deposited AlPO₄ coating”, Nano Energy 2017, 34, 120-130.

56. B. Wang, J. Liu, M.N. Banis, Q. Sun, Y. Zhao, R. Li, T.K. Sham, X. Sun, “Atomic layer deposited lithium silicates as solid-state electrolytes for all solid-state batteries”, ACS Appl. Mater. Interfaces 2017, DOI: 10.1021/acsami.7b07113.

55. C. Cao, S. Mukherjee, J. Liu, B. Wang, M. Amirmaleki, Z. Lu, J.Y. Howe, D. Perovic, X. Sun, C.V. Singh, Y. Sun, T. Filleter, “Role of graphene in enhancing the mechanical properties of TiO2/graphene heterostructures”, Nanoscale 2017, DOI: 10.1039/C7NR03049E.

54. J. Li, J. Liu, Q. Sun, M.N. Banis, X. Sun and T.-K. Sham, “Tracking the effect of sodium insertion and extraction in amorphous and anatase TiO₂ nanotubes”, J. Phys. Chem. C 2017, 121, 11773-11782.

53. A. Lushington, C. Langford, J. Liu, K. Nie, R. Li, X. Sun, J. Guo, and X. Sun, “Orientation and ordering of organic and hybrid inorganic-organic polyurea films using molecular layer deposition”, J. Phys. Chem. C 2017, 121, 11757-11764.

52. J. Liu, B. Wang, M.N. Banis, Z. Wang, R. Li, J. Wang, Y. Hu, T.-K. Shan, and X. Sun, “Investigation of amorphous to crystalline phase transition of sodium titanate by X-ray absorption spectroscopy and scanning transmission X-ray microscopy”, Can. J. Chem. 2017, accepted.

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